Mikrowellenspektren schwingungsangeregter Zustände und allgemeines Valenzkraftfeld von 12C32SF35Cl / Microwave Spectra of Some Vibrational Excited States of 12C32SF35Cl

R. Hamm
1978 Zeitschrift fur Naturforschung A-A Journal of Physical Sciences  
The microwave spectra of some vibrational excited states of CSFC1 were measured with a conventional stark modulation spectrometer. As the spectra of the upper two stretching vibrations could not be found for lack of intensity, the equilibrium structure which had been estimated using Kuchitsu's procedure could not yet be determined. Nevertheless a general internal force field of CSFC1 was obtained, using the inertial defects of the measured excited states in the fit program NCA in addition to
more » ... ration frequencies and centrifugal distortion constants. Moreover, from the determined anharmonic part of the rotation vibration interaction constants, linear relations between some cubic force constants were established
doi:10.1515/zna-1978-0510 fatcat:s4cjhb456nak7o4n2brrjmmugm