Crystal structure of 4-(N,N-dimethyl)aminodithiocarbamoyloxymatrine, C18H29N3OS2

Wei Wang, Zhen-Hua Duan, Jing-Tao Zhang, Bao-Lin Li
2007 Zeitschrift für Kristallographie - New Crystal Structures  
C 18H 29N 3 OS2 ,orthorhombic, P 2 1 2 1 2 1 (no. 19), a =6.6095(5) Å, b =13.1672(9) Å, c =21.467(1) Å, Source of material Carbon disulfide (10 mmol) wasadded to amixture of the sophocarpine (5 mmol) in water (25 ml) and dimethylamine (8 mmol), the reaction mixture wasstirred vigorously at60°Cfor 5hours with amagnetic stirrer. Then the yellow solid product wasf iltrated and dried in vacuum with good yield [1] . The crude product wasfurther purified by column chromatography and eluted with ethyl
more » ... d eluted with ethyl acetate/methanol. The pale-yellow block-shaped crystals of the title compound were obtained by recrystallization from ethanol atroom temperature.
doi:10.1524/ncrs.2007.0100 fatcat:ozzwbqhyqvf7hosrd5l56644rq