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Department of Chemistry, Nagpur University, Nagpur Manuscript received 10 July 1974; accepted 10 October 1974 Interaction of carbonyl sulphide with p-chlorophenyl and \(p\)-tolyl guanidines in presence of alkyl halides has been shown to afford the related alkyl guanyl thiocarbamates. These on reaction with amines eliminate mercaptan and form the corresponding amidino carbamides.doi:10.5281/zenodo.6404447 fatcat:4xc62a3yfbdkhcaaqhxkn5a2na