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Perovskite oxides are widely studied for a variety of applications, from theromoelectrics to fuel cells. Part of the attraction lies in the fact that perovskite ceramics are relatively easy to dope chemically over a wide range of compositions, resulting in various degrees of structural ordering . As a consequence, the properties and functionalitiesof such materials can be readily tailored  . For instance in systems proposed for thermoelectric applications, the presence of superlattices,doi:10.1017/s1431927616002166 fatcat:i7ktb7fg4nb6bfep3as6sjrarm