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Brownian motion, hydrodynamics, and the osmotic pressure
1993
Journal of Chemical Physics
It is shown that the osmotic pressure of a colloidal dispersion can be interpreted as the isotropic part of the macroscopic particle stress in the suspension. The particle stress is in turn expressible in terms of hydrodynamic interactions among the suspended particles. Thus, there is a completely mechanical definition of the osmotic pressure, just as there is for the pressure in a molecular fluid. For an equilibrium suspension of colloidal particles subjected to thermal Brownian forces, this
doi:10.1063/1.464105
fatcat:xndc5oa3ozen3ok56sd3mhvfce