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Quantum Oscillations of the Total Spin in a Heterometallic Antiferromagnetic Ring: Evidence from Neutron Spectroscopy
2007
Physical Review Letters
Using inelastic neutron scattering and applied fields up to 11.4 T, we have studied the spin dynamics of the Cr 7 Ni antiferromagnetic ring in the energy window 0.05-1.6 meV. We demonstrate that the external magnetic field induces an avoided crossing (anticrossing) between energy levels with different total-spin quantum numbers. This corresponds to quantum oscillations of the total spin of each molecule. The inelastic character of the observed excitation and the field dependence of its
doi:10.1103/physrevlett.98.167401
pmid:17501458
fatcat:tksfzd5zqbgsdkq4qpyxevlzla