We consider the low-temperature expansion of the Casimir-Polder free energy for an atom and graphene by using the Poisson representation of the free energy. We extend our previous analysis on the different relations between chemical potential μ and mass gap parameter m. The key role plays the dependence of graphene conductivities on the μ and m. For simplicity, we made the manifest calculations for zero values of the Fermi velocity. For μ>m, the thermal correction ∼T2, and for μ<m, we confirm

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... e recent result of Klimchitskaya and Mostepanenko, that the thermal correction ∼T5. In the case of exact equality μ=m, the correction ∼T. This point is unstable, and the system falls to the regime with μ>m or μ<m. The analytical calculations are illustrated by numerical evaluations for the Hydrogen atom/graphene system.