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U- to Z-shape isomerization in a Pt2Ag2 framework containing pyridyl-NHC ligands
2018
Dalton Transactions
Preserved Fulltext
A highly twisted U-shaped Pt2Ag2 complex bearing pyridyl–NHC ligands showed isomerization to Z-shaped conformations via an intermolecular process. 1H NMR experiments revealed that the isomerization reached U : Z = 2 : 1 ratio in a thermodynamic equilibrium state.
doi:10.1039/c8dt01047a
pmid:29713705
fatcat:bbrbyj6aijdwnf2tnwyszlgt2m