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Kinetics and mechanism of oxidation of L-arginine by diperiodatonickelate(IV) in aqueous alkaline medium
P. G. Department of Studies in Chemistry, Karnatak University, Dharwad-580 003, India Manuscript received 31 March 1998, revised 9 July 1998, accepted 20 July 1998 Oxidation of L-arginine by diperiodatonickelate(lv) (DPN) in aqueous alkaline medium is first order in [DPN], but fractional order each in [L-Arg] and [OH-]. The rate of reaction decreases in the decrease in the dielectric constant of the medium. Added products and variation of ionic strength have no significant effect on the rate ofdoi:10.5281/zenodo.5852221 fatcat:lbxbycdjq5ghdgxe4virfxlhp4