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(À)-Petrosiol E, a metabolite of sponge Petrosia strongylata, has been synthesized in 32% overall yield from cheap natural D-xylose in 10 steps. Our strategy provides an efficient way for the total synthesis of other petrosiol members, featuring the three contiguous stereogenic centers are easily constructed from D-xylose chiral template.doi:10.1016/j.tet.2014.09.030 fatcat:nqgw2naxpresxfhaeafs2fkdgq