Synthetic Access to a Novel Binaphthyl Ligand Bearing a Phosphine and a Triazole Donor Site

Claudia May, Yu Sun, Gotthelf Wolmershäuser, Werner R. Thiel
2009 Zeitschrift für Naturforschung. B, A journal of chemical sciences  
The combination of a diphenylphospinyl and a triazol-3-yl unit was realized for the first time at a 1,1'-binaphthyl backbone. This novel type of P,N-ligand is accessible as an enantiomerically pure compound in just a few steps. First experiments on the coordination chemistry with palladium(II) chloride have been carried out. A series of intermediates and a binuclear palladium(II) complex could be characterized by X-ray crystal structure analysis
doi:10.1515/znb-2009-11-1226 fatcat:y7t72tk2xrba7nnqmcrxdcr3xy