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Photon Correlation Spectroscopy is used to study the AOT microemulsion with and without NaCl. Collective diffusion coefficient was investigated by Photon Correlation Spectroscopy technique. We have studied effect of charge on dynamic of water-in-oil microemulsion (nano-droplet of water to the oil), which stabilized by AOT and dispersed in n-Decane at water/AOT with 6.7 molar ratio. The small angle X-ray scattering technique and hard sphere model were used to study the structural information ofdoi:10.4236/opj.2012.21008 fatcat:lva6pk2zsbgwnba3yugke433fq