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Synthesis and Characterization of Well-Defined PEGylated Polypeptoids as Protein-Resistant Polymers
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unpublished
Well-defined polypeptoids bearing oligomeric ethylene glycol side chains 11 PNMe(OEt) n G (n = 1-3) with controlled molecular weight (3.26-28.6 kg/mol) and narrow 12 molecular distribution (polydispersity index, PDI = 1.03-1.10) have been synthesized by ring-13 opening polymerization of the corresponding N-carboxyanhydrides having oligomeric ethylene 14 glycol side chains (Me(OEt) n -NCA, n = 1-3) using primary amine initiators. Kinetic studies of 15 polymerization revealed a first-order
doi:10.1021/acs.biomac.6b01824.s001
fatcat:vhitvimwavbnjkeyyaraxx5vcm