Structure and Nonlinear Optical Properties Study of 2-Amino-5-Chlorobenzophenone: (A Spectroscopic Approach)

C John, D Manimaran, I Joe, George Lukose, Sherifa Rahim
2016 Oriental Journal of Chemistry  
The FT-IR and FT-Raman spectra of 2-amino-5-chlorobenzophenone have been recorded and analyzed. Structural geometry, vibrational wavenumbers and first-order hyperpolarizability were computed using density functional theory method. N-H ... O distance shows the possibility of intramolecular hydrogen bonding. Natural bond orbital analysis confirms the presence of the N-H ... O hydrogen bonding. The computed first-order hyperpolarizability value suggests that 2-amino-5chlorobenzophenone has a
more » ... phenone has a potential for producing the second harmonic generation.
doi:10.13005/ojc/320172 fatcat:iqyvrufecfb5pe3lvtwrc7l4oq