Semiconductor superlattices (SL) may be described by a Boltzmann-Poisson kinetic equation with a Bhatnagar-Gross-Krook (BGK) collision term which preserves charge, but not momentum or energy. Under appropriate boundary and voltage bias conditions, these equations exhibit time-periodic oscillations of the current caused by repeated nucleation and motion of charge dipole waves. Despite this clear nonequilibrium behavior, if we 'close' the system by attaching insulated contacts to the superlattice

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... and keeping its voltage bias to zero volts, we can prove the H theorem, namely that a free energy Φ(t) of the kinetic equations is a Lyapunov functional (Φ≥ 0, dΦ/dt≤ 0). Numerical simulations confirm that the free energy decays to its equilibrium value for a closed SL, whereas for an 'open' SL under appropriate dc voltage bias and contact conductivity Φ(t) oscillates in time with the same frequency as the current self-sustained oscillations.