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Protein tag; Dopamine; Cyclic voltammetry; Electrochemical probe; Spectrofluorimetry. KEYWORDS ABSTRACT A simple strategy for studying electrochemical properties of proteins or peptides using unmodified carbon paste electrodes was developed by cross-linking dopamine (DA) with BSA as a test protein. The BSA-5-Cys-DA adducts produced were evaluated by cyclic voltammetry, spectrofluo-rometry and first-derivative spectrophotometry in the visible range. An anodic peak was observed after proteinfatcat:ca5pcp2sqjfuzbyx4qamodwflm