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Electronic Correlations, Jahn-Teller Distortions and Mott Transition to Superconductivity in Alkali-C60Compounds
2012
EPJ Web of Conferences
The discovery in 1991 of high temperature superconductivity (SC) in A3C60 compounds, where A is an alkali ion, has been rapidly ascribed to a BCS mechanism, in which the pairing is mediated by on ball optical phonon modes. While this has lead to consider that electronic correlations were not important in these compounds, further studies of various AnC60 with n=1, 2, 4 allowed to evidence that their electronic properties cannot be explained by a simple progressive band filling of the C60
doi:10.1051/epjconf/20122300015
fatcat:2wyi37lgo5cjdkujdsskwh2ef4