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Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex
2013
Asian Journal of Chemistry
Preserved Fulltext
A novel carboxy-functionalized diiron dithiolate complex, [(µ-SCH2)2NCH2CH2CO2CH2CH2Cl][Fe2(CO)6] (I) as active site model of [FeFe]-hydrogenase, has been successfully synthesized by condensation reaction of [(µ-SCH2)2NCH2CH2CO2H][Fe2(CO)6] (A) with HOCH2CH2Cl in the presence of 4-dimethylaminopyridine and dicyclohexylcarbodiimide. Its structure was characterized by combustion analysis, ESI-MS, IR and 1 H ( 13 C) NMR spectroscopic techniques.
doi:10.14233/ajchem.2013.14537
fatcat:77vtll66rzdobht7fd7hrph5pi