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The intriguing dual-directing effect of 2-cyanobenzyl ether for a highly stereospecific glycosylation reaction
The diverse presence as well as their very specific bio-responses of glycoconjugates found in all living species requires scientists to synthesize the precise structure of these complex oligosaccharides for various studies on glycoscience. Very few approaches were able to offer the sole aor b-glycosylated products, even at the cost of complicating the preparative route or usage of exotic chiral auxiliaries to drive the stereoselectivity. In this report, the unification of solvent assistance anddoi:10.1038/ncomms6051 pmid:25277946 fatcat:d7pv7zp2nbdsbhzyxzqj32gr6e