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Abnormally aggregation-induced emissions observed from hydrogen- and silyl-substituted siloles
2020
Main Group Metal Chemistry
AbstractSilacyclopentadienes (siloles) are currently of great interest because of their intriguing aggregation-induced emission (AIE) characteristics. In this work, abnormally AIE phenomena were observed from silyl- and hydrogen-substituted siloles respectively. We propose silyl-substituent and hydrogen atom effects to explain this via both experiments and theoretical calculations. It was discovered that trimethylsilyl substituents destroyed the p-interactions with the silole core and resulted
doi:10.1515/mgmc-2020-0015
fatcat:s57c4kislfbu5ak5fmjm4mxzii