Methacryloyl chloride was grafted onto lignocresol to increase the acyl content of lignocresol and to enhance the interfacial compatibility of lignocresol and polylactic acid. The physical and mechanical properties of the modified lignocresol sample were studied. The methacryloyl-modified lignocresol was characterized by infrared spectroscopy (IR), ultravioletvisible (UV) spectroscopy, and gel permeation chromatography (GPC). Unmodified and modified lignocresol samples were used to prepare

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... site films with polylactic acid, and its tensile strengths and elongations at breaks were analyzed after film formation. Thermal stabilities were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that methacryloyl group was successfully grafted onto lignocresol, and that the optimum dosage of methacryloyl chloride required was 0.5 mL per 0.5 g of lignocresol. When unmodified lignocresol was added to polylactic acid, the tensile strength gradually decreased as the amount of lignocresol increased. However, the composite films prepared from the methacryloylmodified lignocresol exhibited a slower decline in tensile strength and displayed an increased elongation at break. The optimum mechanical properties were found using a 10% blend of modified lignocresol with polylactic acid.