Charge transport and recombination in bulk heterojunction solar cells studied by the photoinduced charge extraction in linearly increasing voltage technique

A. J. Mozer, N. S. Sariciftci, L. Lutsen, D. Vanderzande, R. Österbacka, M. Westerling, G. Juška
2005 Applied Physics Letters  
G. (2005) . Charge transport and recombination in bulk heterojunction solar cells studied by the photoinducted charge extraction by linearly increasing voltage technique. Applied Physics Letters, 86 (11), 1-3. Charge transport and recombination in bulk heterojunction solar cells studied by the photoinducted charge extraction by linearly increasing voltage technique Abstract Charge carriermobility and recombination in a bulk heterojunctionsolar cell based on the mixture of
more » ... imethyloctyloxy)-phenylene vinylene] (MDMO-PPV) and 1-(3-methoxycarbonyl)propyl-1-phenyl-(6,6)-C 61 (PCBM) has been studied using the novel technique of photoinduced charge carrier extraction in a linearly increasing voltage (Photo-CELIV). In this technique, charge carriers are photogenerated by a short laser flash, and extracted under a reverse bias voltage ramp after an adjustable delay time (t del ). The Photo-CELIV mobility at room temperature is found to be μ = 2 × 10 −4 cm 2 V −1 s −1 , which is almost independent on charge carrier density, but slightly dependent on tdel. Furthermore, determination of charge carrier lifetime and demonstration of an electric field dependent mobility is presented.
doi:10.1063/1.1882753 fatcat:r3dgb2lqavf6bdhvc7dc242zym