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A comprehensive empirical analysis based on exact quantum simulations of all available total absorption coefficient and branching-ratio data for the UV photodissociation spectra of HI and DI has been used to determine the potential energy curves of the four excited electronic states A 1 ⌸ 1 , a 3 ⌸ 0 ϩ, a 3 ⌸ 1 , and t 3 ⌺ 1 ϩ , and the associated transition moment functions. It is shown that there is no need to invoke coupling among the various final-state wave functions to explain the data.doi:10.1063/1.1513303 fatcat:dgcago5ggbcu5eaurrbempipn4