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Two new red-degraded bands in the room-temperature vacuum-ultraviolet absorption spectrum of carbon monoxide have been identified in the 94 000-94 500 cm −1 energy region and analyzed. One of the bands at Ϸ94 225 cm −1 ͑106.1 nm͒ has three observable bandheads and is partially overlapped with the strong C 1 ⌺ + -X 1 ⌺ + ͑1-0͒ transition at lower energy. It is assigned to the c 3 ⌸ -X 1 ⌺ + ͑1-0͒ transition. The other band at Ϸ94 437 cm −1 ͑105.9 nm͒ with one clear bandhead is assigned to the kdoi:10.1063/1.2136869 pmid:16392915 fatcat:hey2dxgx2bcgjg7bxcnksv2zou