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Preprints of symposium on liquid crystals
The temperature dependence of the spin-lattice relaxation time T 1 is investigated in the enantiomer and the racemate of 4-(1-methylhexyloxycarbonyl)phenyl 4'-octyloxybiphenyl-4-carboxylate (MH(6)POBC) by solid-state 13 C-NMR spectroscopy. In the case of the enantiomer, the T 1 of an aromatic carbon belonging to the core part of the liquid-crystalline molecule decreases from 1 s to 0.2 s with decreasing temperature in smectic phases, where the frequency of the molecular rotation around its longdoi:10.11538/ekitou.2011.0.151.0 fatcat:p77nqggld5ba5droqzhamtwbei