A new gelator based on tetraphenylethylene and diphenylalanine: Gel formation and reversible fluorescence tuning

Fei Sun, GuanXin Zhang, DeQing Zhang
2012 Chinese Science Bulletin  
A new gelator 1 based on tetraphenylethylene (TPE) and diphenylalanine was designed and synthesized. Compound 1 was non-emissive in solution, but its fluorescence turned on after the formation of gels, due to the aggregation-induced emission (AIE) feature of TPE. Interestingly, the fluorescence was reversibly switched "on-off" upon the "gel-sol" transition. Scanning electron microscope (SEM), confocal laser scanning microscope (CLSM) and X-ray diffraction (XRD) were employed to study the gels.
more » ... etraphenylethylene, diphenylalanine, gel, aggregation-induced emission (AIE) Citation: Sun F, Zhang G X, Zhang D Q. A new gelator based on tetraphenylethylene and diphenylalanine: Gel formation and reversible fluorescence tuning. Chin Sci Bull, 2012, 57: 42844288,
doi:10.1007/s11434-012-5430-6 fatcat:lg63zdwdcjatjgi2adkbvy6dhu