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Katalytische Synthese von Hydridmagnesiumchlorid aus Magnesium, Wasserstoff und Magnesiumchlorid/ Catalytic Synthesis of Hydridomagnesium Chloride from Magnesium, Hydrogen and Magnesium Chloride
1984
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Preserved Fulltext
THF solutions of hydridomagnesium chloride (HMgCl, 1a) can be prepared in nearly quantitative yields by hydrogenation of magnesium in THF solutions of magnesium chloride at 0 °C in the presence of a CrCl3-Mg anthracene catalyst. Concentration of saturated HMgCl solutions, or hydrogenation of magnesium under the above mentioned conditions in MgCl2-THF suspensions, lead to the formation of THF solutions of species having the approximate com position HMgCl · MgH2 or 2 HMgCl · MgH2.
doi:10.1515/znb-1984-0802
fatcat:4v7bm2jwqnfl7ncf7akpdcyfki