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Polarized Cu K x-ray absorption near-edge structure spectra of CuO are measured and analyzed with the aim of extracting quadrupole and dipole partial spectral components. Theoretical spectral components are calculated within the framework of real-space multiple-scattering technique, relying on a non-self-consistent muffintin potential. A local coordinate system xЈyЈzЈ suitable for polarization analysis is defined by the sides of the CuO 4 quasirectangle rather than by directions of the Cu-Odoi:10.1103/physrevb.63.045104 fatcat:alm6y2akoncrhm7dt4quhknjrq