Time Reversibility, Correlation Decay and the Steady State Fluctuation Relation for Dissipation

Debra Searles, Barbara Johnston, Denis Evans, Lamberto Rondoni
2013 Entropy  
Steady state fluctuation relations for nonequilibrium systems are under intense investigation because of their important practical implications in nanotechnology and biology. However the precise conditions under which they hold need clarification. Using the dissipation function, which is related to the entropy production of linear irreversible thermodynamics, we show time reversibility, ergodic consistency and a recently introduced form of correlation decay, called T-mixing, are sufficient
more » ... tions for steady state fluctuation relations to hold. Our results are not restricted to a particular model and show that the steady state fluctuation relation for the dissipation function holds near or far from equilibrium subject to these conditions. The dissipation function thus plays a comparable role in nonequilibrium systems to thermodynamic potentials in equilibrium systems.
doi:10.3390/e15051503 fatcat:nevjav3bwfhhpgiaetha2kopyq