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Synthesis and Molecular Properties of Partially Fluorinated DNTTs
[post]
2020
unpublished
Preserved Fulltext
1,2,3,4-Tetrafluoro-dinaphthothienothiophene (F4DNTT) and 1,2,3,4,8,9,10,11-octafluoro-dinaphthothienothiophene (F8DNTT) were synthesized via bisthiomethyl alkene intermediates which were accessible by McMurry coupling or Wittig olefination of partially fluorinated naphthalene precursors. DFT-based electronic structure calculations, X-ray absorption spectroscopy (NEXAFS) and UV/Vis measurements were used for HOMO/LUMO gap determination and to analyse the electronic structures of the partially
doi:10.26434/chemrxiv.13385351.v1
fatcat:hk5w23okc5fxhc266euyenyxva