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The cyclic ground state structure of the HF trimer revealed by far infrared jet-cooled Fourier transform spectroscopy
2014
Physical Chemistry, Chemical Physics - PCCP
Preserved Fulltext
The rovibrationally resolved Fourier transform (FT) far infrared (FIR) spectra of two intermolecular librations of (HF) 3 , namely the in-plane 6 and out-of-plane 4 bending fundamentals centered respectively at about 494 cm -1 and 602 cm -1 ,have been measured for the first time underjet-cooled conditions using the supersonic jet of the Jet-AILES apparatus. The simultaneous rotational analysis of 245 infrared transitions belonging to both bands enabled to determine the ground state (GS), 6 and 4 rotational and centrifugal distortion
doi:10.1039/c3cp55047h
pmid:24469411
fatcat:btpkdedxzfab5ehlch4vq5jpsm