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Highly dispersed and uniform palladium nanowire networks (NWNs) are synthesized by a controllable, templateless and polyelectrolyte-mediated self-assembly process. In this method, anisotropic Pd 2+ -polysodium-p-styrenesulfonate (PSS) networks are assembled between Pd 2+ ions and SO − 3 attached to the pendent aromatic ring of PSS in solution by an electrostatic attraction. Reduction of Pd(II) cations to metallic Pd(0) leads to the formation of Pd nanostructures from cubic nanoparticles todoi:10.1088/0957-4484/19/45/455602 pmid:21832779 fatcat:xeaxhsdg2fa33htyrbm22zdeoa