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Adsorption of solutes at liquid–vapor interfaces: insights from lattice gas models
2013
Faraday discussions
The adsorption behavior of ions at liquid-vapor interfaces exhibits several unexpected yet generic features. In particular, energy and entropy are both minimum when the solute resides near the surface, for a variety of ions in a range of polar solvents, contrary to predictions of classical theories. Motivated by this generality, and by the simple physical ingredients implicated by computational studies, we have examined interfacial solvation in highly schematic models, which resolve only coarse
doi:10.1039/c2fd20106b
pmid:23795493
fatcat:qrhsa47cwvbvrotpc54qxq6orm