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Two-particle spectroscopy with correlated electron pairs is used to establish the causal link between the secondary electron spectrum, the (π+σ)-plasmon peak and the unoccupied band structure of highly oriented pyrolitic graphite. The plasmon spectrum is resolved with respect to the involved interband transitions and clearly exhibits final state effects, in particular due to the energy gap between the interlayer resonances along the ΓA-direction. The corresponding final state effects can alsoarXiv:2006.05413v1 fatcat:4uru7l3tqrclpf62dhybjuvzmu