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Journal of Chemical Engineering of Japan
A kinetic study was performed on the bulk thermal polymerization of styrene. The conversion and average molecular weights were measured. Rate equations were derived on the basis of a modelproposed in a previous paper which introduced the gel effect into each elementary reaction by considering the decrease of segmental jump frequency during polymerization. The model could successfully simulate the conversion and the average molecular weight. Experimental results for the facilitated transport ofdoi:10.1252/jcej.19.413 fatcat:i2vydb3zjbbizaoxtap2qgohvi