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Frenkel line and solubility maximum in supercritical fluids
2015
Physical Review E
A new dynamic line, the Frenkel line, has recently been proposed to separate the supercritical state into rigid-liquid and non-rigid gas-like uid. The location of Frenkel line on the phase diagram is unknown for real uids. Here, we map the Frenkel line for three important systems: CO2, H2O and CH4. This provides an important demarcation on the phase diagram of these systems, the demarcation that separates two distinct physical states with liquid-like and gas-like properties. We find that the
doi:10.1103/physreve.91.012112
pmid:25679575
fatcat:gkkafytbxverneayl6kzoum5ke