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Structure and Dynamics of Loosely Cross-Linked Ionic Microgel Dispersions in the Fluid Regime
2012
Physical Review Letters
We report a comprehensive experimental-theoretical study of the temperature-and concentrationdependent swelling behavior of weakly cross-linked PNiPAm ionic microgel particles in the deionized fluid phase. The particles swell reversibly when the dispersion is cooled from the collapsed state to lower temperatures. While the collapsed state shows no dependence on the microgel number density, the swelling at lower T is more pronounced at lower concentrations. The static pair correlations and
doi:10.1103/physrevlett.109.048302
pmid:23006114
fatcat:aui7s4h7qvbmros7yihbpsgrja