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Substitution of Conventional High-temperature Syntheses of Inorganic Compounds by Near-room-temperature Syntheses in Ionic Liquids
2013
Zeitschrift für Naturforschung. B, A journal of chemical sciences
The high-temperature syntheses of the low-valent halogenides P2I4, Te2Br, a-Te4I4, Te4(Al2Cl7)2, Te4(Bi6Cl20), Te8(Bi4Cl14), Bi8(AlCl4)2, Bi6Cl7, and Bi6Br7, as well as of WSCl4 and WOCl4 have been replaced by resource-efficient low-temperature syntheses in room temperature ionic liquids (RTILs). The simple one-pot syntheses generally do not require elaborate equipment such as two zone furnaces or evacuated silica ampoules. Compared to the published conventional approaches, reduction of
doi:10.5560/znb.2013-3141
fatcat:qnn6s53ovfhm7caqk7lphlb7za