Estimation of Acid-Hydrolyzed Cellulose Fiber Size Distribution with Exponential and Rosin-Rammler (R-R) Laws

Weijiang Duan, Zhong Liu, Pengtao Liu, Lanfeng Hui
2018 BioResources  
A new method was developed to characterize the cellulose fiber (hardwood dissolving pulp) size distribution after 50 wt% sulfuric acid hydrolysis at different hydrolysis temperatures with exponential and Rosin-Rammler (R-R) laws. The results show that the two above laws can be effective to explain the cellulose hydrolysis process. The exponential and the R-R laws were found to be well fitted to the sulfuric acid hydrolyzed cellulose fiber length distribution. The cumulative number distribution
more » ... rom Fiber Tester was shown to fit the exponential distribution well, while the cumulative mass distribution obtained from the acid hydrolysis was found to be suitable to the R-R law via an approximation process. The results from SEM analyses also supported the above conclusions. This approach can be used to characterize the cellulosic fiber properties before a further process of biorefinery, nanocellulose preparation, or other application of lignocellulosic fibers.
doi:10.15376/biores.13.4.7792-7804 fatcat:besazegurndi7fmmonc2ja6xxe