Wideline 1H NMR Study on Hydrated Layered Sulfides K0.5(H2O)y[NbS2] and Na0.5(H2O)y[NbS2]

Anton Lerf, Paul Burkert, Jürgen O. Besenhard, Robert Schöllhorn
1977 Zeitschrift für Naturforschung. B, A journal of chemical sciences  
H NMR spectra of different hydration stages show that the water molecules in hydrated layered niobium sulfides A0.5(H2O)y[NbS2] are rather mobile at room temperature. A structural scheme of water arrangement in the interlayer space is proposed with the C2-axis of the H2O molecules parallel to the basal planes of the NbS2 layer units.
doi:10.1515/znb-1977-0916 fatcat:coozmkcajnemxkcen2dou4p7ye