Neutral and cationic germanium(IV) fluoride complexes with phosphine coordination – synthesis, spectroscopy and structures

Rhys King, William Levason, Gillian Reid
2021 Dalton Transactions  
The neutral complexes, trans-[GeF4(PiPr3)2], [GeF4(2-L)] (L = CH3C(CH2PPh2)3 or P(CH2CH2PPh2)3) are obtained from [GeF4(MeCN)2] and the ligand in CH2Cl2. Treatment of [GeF4(PMe3)2] with n equivalents of TMSOTf (Me3SiO3SCF3) leads to...
doi:10.1039/d1dt03339e pmid:34812814 fatcat:ff34ept7vbazdplmdznpuq7mgu