A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2018; you can also visit the original URL.
The file type is
Results of mass spectrometric measurements are reported which characterize the chemical bonding in the radical cations (CH3SiH)'+ and (CH3)2Si'+ and provide evidence for the existence of the corresponding neutral silylene molecules CH3SiH and (CH3)zSi in the gas phase. The experiments were performed with a modified four-sector ZAB mass spectrometer with a BEBE configuration and collision cells mounted in the intermediate field-free regions B(l)/E( l), E( l)/B(2), and B(2)E(2). Observeddoi:10.1021/j100153a036 fatcat:m32cc45znjc6zejxunfzjbufba