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Journal of Synthetic Organic Chemistry, Japan
Preparation of optically active, highly functionalized carbocycles is an important issue in recent synthetic organic chemistry . Ferrier's carbocyclization reaction , which provides optically pure cyclohexanones from aldohexoses , is one of the most efficient procedures for this purpose. Chiral and highly oxygenated cyclohexanes obtained by this reaction are potentially versatile chiral building blocks in natural product synthesis . In this article , the development of catalytic Ferrier'sdoi:10.5059/yukigoseikyokaishi.53.858 fatcat:jmvil53jb5egdfg7kdpkqzd7m4