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The preparation of polymer membrane selective to silver ion and its application to ion-selective electrode is reported here. PVC membrane contain silver-selective calixarene derivative as ionophore. The membrane electrode is highly selective to silver ion and exhibit good linear response over a wide concentration range of 1.0×10 -1 to 1.0×10 -5 M AgNO 3 with Nernstian slope of 58.9 mV per decade. The detection limit of electrode is 6.31×10 -6 M .The calixarene based membrane electrodedoi:10.3390/s21000417 fatcat:gyyquj26vndnfmumznq6x7zjmi