TREATMENT BY ALTERNATIVE METHODS OF REGRESSION GAS CHROMATOGRAPHIC RETENTION INDICES OF 35 PYRAZINES

Khadidja Amirat Fatiha Mebarki
2020 Zenodo  
The study treated two closer alternative methods of which the principal characteristic: a non-parametric method (the least absolute deviation (LAD)) and a traditional method of diagnosis OLS.This was applied to model, separately, the indices of retention of the same whole of 35 pyrazines (27 pyrazines with 8 other pyrazines in the same unit) eluted to the columns OV-101 and Carbowax-20M, by using theoretical molecular descriptors calculated using the software DRAGON. The detection of
more » ... ction of influential observations for non-parametric method (LAD) is a problem which has been extensively studied and offers alternative dicapproaches whose main feature is the robustness .here is presented and compared with the standard least squares regression .The comparison between methods LAD and OLS is based on the equation of the hyperplane, in order to confirm the robustness thus to detect by the meaningless statements and the points of lever and validated results in the state approached by the tests statistics: Test of Anderson-Darling, shapiro-wilk, Agostino, Jarque-Bera, graphic test (histogram of frequency) and the confidence interval thanks to the concept of robustness to check if the distribution of the errors is really approximate.
doi:10.5281/zenodo.4326529 fatcat:wol3lmz5sbglrb7mw4ijwmjpqi