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High-resolution powder X-ray diffraction and density functional plane wave pseudopotential techniques have been used to obtain an optimized structural model of silver arachidate, [Ag(O 2 C(CH 2 ) 18 CH 3 ] 2 . The unit cell is triclinic, space group P-1 with cell dimensions of a = 4.1519(10) Å, b = 4.7055(10) Å, c = 53.555(4) Å, á = 89.473(15)˚, â = 87.617(5)˚, ã = 76.329(5)˚. The structure is characterized by an 8-membered ring dimer of Ag atoms and carboxyl groups joined by four-member Ag-Odoi:10.1017/s0885715612000309 fatcat:kb6pkhzbibha7exxlwgkxrxffm