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More than ten years ago, Manners and coworkers published the first experimental study on the efficiency of titanocene to catalyze the dehydrocoupling of dimethylamine borane (DMAB, T. Clark, C. Russell and I. Manners, J. Am. Chem. Soc., 2006, 128, 9582–9583).doi:10.1039/c8cp01970c pmid:29846373 fatcat:yfqftcozj5ckbeqng57cbykbva