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High-level ab initio potential energy curves are calculated for the RG + -He complexes (RG =Ar-Rn). RCCSD(T) calculations are employed with large basis sets, and taking account of spin-orbit coupling. The calculated spectroscopic parameters are compared to experimentally-determined values, to other high-level ab initio results, and to results from potentials that were obtained by fitting to experimental data. The gas-phase mobilities of RG + ions in He are calculated from our potentials anddoi:10.1080/00268970903183433 fatcat:pm5lm6gbvvg5vdaiwwxehyoloq