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The break-down of metals vapour (Al, Cu) are simulated near the break-down threshold values of laser radiation. The approximations of collision-radiation model are used, including the detail kinetics of exited states with radiation and collision transitions, step-by-step ionisation process, unexitation and recombination. Energy balance is based on two-temperature approximation : for electrons and for heavy particles. It is shown that the particles concentration in exited states and plasmadoi:10.1051/jp4:1994421 fatcat:ebgafcqxnrcp5ktaf3yvt3zx7e