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Smectic behaviour of methyl 4-alkoxybenzoates with a partially fluorinated alkyl chain
A series of 4-alkoxybenzoic acids 1[m,n] and their methyl esters 2[m,n] containing a partially fluorinated alkyl chain was prepared and their physical properties were investigated by optical, thermal and powder X-ray diffraction (XRD) methods. The former exhibits an SmC phase, while the latter form an SmA phase. XRD analysis indicated liquid-like character of the linking alkyl chains, and showed a decreasing layer thermal expansion coefficient from positive to negative upon increasing thedoi:10.6084/m9.figshare.4738504.v1 fatcat:fpokrl5uuvgebft7el66hrenea